University of Kentucky - Advanced Chemistry 

1.01 The Rate of Chemical Reactions

1.02 Comparing Rate of Change for Reactants and Products

1.02a Obtaining a Rate Law from Experimental Data Equations

1.03 The Rate Law

1.04 Obtaining a Rate Law from Experimental Data

1.04a Rate Law Calculations

1.05 First-Order Kinetics and the Integrated Rate Law

1.05a Graphic 1st Order

1.06 First-Order Kinetics and the Half-Life

1.07 Second-Order Reactions

1.07a Graphics 2nd Order

1.08 Collision Theory

1.08a Activation Energy

1.09 The Arrhenius Equation

1.09a Graphic Activation Energy

1.10 Reaction Mechanisms

1.10a RDS Fast Equilibrium

1.10b Rate Determining Step

1.11 Catalysis

Syllabus

Kinetics Lecture Notes and Practice Problems

Kinetics

2.01 Dynamic Equilibrium

2.02 Law of Mass Action

2.03 Law of Mass Action for Combined Reactions

2.04 Relationship Between Kc and Kp

2.04a Relationship Between Kc and Kp

2.05 Calculating the Equilibrium Constant

2.05a Finding Kc

2.06 Reaction Quotient

2.06a Predicting Reaction Progress with the Reaction Quotient

2.07 Calculating Equilibrium Concentrations

2.07a Finding Equilibrium Concentrations, part 1

2.07b Finding Equilibrium Concentrations, part 2

2.07c Finding Equilibrium Concentrations, part 3

2.08 Le Chatelier's Principle Part A

2.08a Le Chatelier's Principle Part B

2.08b How Changes Shift the Equilibrium

Chemical Equilibrium Lecture Notes and Practice Problems

Chemical Equilibrium

3.01 Acids and Bases

3.02 pH and Kw

3.02a Finding Kw

3.03 Acid Strength

3.04 Finding pH

3.05 Strong and Weak Bases

3.05a Calculating equilibrium concentrations of a weak base, part 1

3.05b Calculating equilibrium concentrations of a weak base, part 2

3.06 Ions as Acids and Bases

3.06a Acid-base properties of aqueous salts, part 1

3.06b Acid-base properties of aqueous salts, part 2

3.06c Acid-base properties of aqueous salts, part 3

3.07 Types of Acids

3.08 Polyprotic Acids

Acid-Base Equilibria Lecture Notes and Practice Problems

Acid-Base Equilibrium

4.01 Buffers and the Common Ion Effect

4.02 pH of Buffer Solutions

4.02a Aqueous Equilibria Worked Example 1

4.03 Buffer Action

4.03a Aqueous Equilibria Worked Example 2

4.03b Aqueous Equilibria Worked Example 3

4.04 Buffer: Preparation and Capacity

4.05 Strong Acid - Strong Base Titration

4.06 Titrations Involving Either a Weak Acid or a Weak Base

4.06 Part 1 Aqueous Equilibria Worked Example

4.06 Part 1.a - Aqueous Equilibria Worked Example

4.06 Part 1.b - Aqueous Equilibria Worked Example

4.06 Part 1.c - Aqueous Equilibria Worked Example

4.06 Part 1.f Aqueous Equilibria Worked Example

4.06 Part 1.h Aqueous Equilibria Worked Example

4.06 Part 2.a Aqueous Equilibria Worked Example

4.06 Part 2.b Aqueous Equilibria Worked Example

4.07 Polyprotic Acid Titrations

4.08 Indicators

4.09 Solubility Equilibria

4.10 Molar Solubility and the Solubility Product

4.10.a Aqueous Equilibria Worked Example

4.11 Molar Solubility and the Common Ion Effect

4.11 2.b - Aqueous Equilibria Worked Example

4.11 2.c Aqueous Equilibria Worked Example

4.12 The Effect of pH on Solubility

4.12.b Aqueous Equilibria Worked Example

4.12c Aqueous Equilibria Worked Example

4.13 Precipitation Reaction and Selective Precipitation

4.13a Aqueous Equilibria Worked Example

Aqueous Equilibria Lecture Notes and Practice Problems

Aqueous Equilibria

5.01 Review of Thermochemistry

5.01a Enthalpy of Reaction Refresher

5.02 Spontaneous vs. Nonspontaneous

5.10 Standard versus Nonstandard Free Energy Change

5.03 The Second Law of Thermodynamics

5.04 Entropy

5.05 Entropy of the Universe

5.06 Gibbs Free Energy

5.06a Gibbs Free Energy Example Problem 1

5.06b Gibbs Free Energy Example Problem 2

5.07 The Third Law of Thermodynamics

5.08 Calculating Standard Entropy Change

5.08a Thermodynamics Worked Example

5.09 Calculating Standard Free Energy Change

5.09a Thermodynamics Worked Example

5.09b Thermodynamics Worked Example

5.11 Comparing ?G° and K

5.10a Thermodynamics Worked Example

5.10b Thermodynamics Worked Example

5.02a Spontaneous vs Nonspontaneous Example Problem

Thermodynamics Lecture Notes and Practice Problems

Thermodynamics

Advanced Chemistry Final Assessment