Hydrocyanic Acid: Overview, Questions, Preparation

Chemical Equilibrium 2021

Updated on Jun 4, 2024 16:02 IST

Hydrocyanic acid is a hydrogen cyanide fluid in the water. The hydrocyanic acid formula is HCN. Hydrocyanic acid is a colourless liquid that fumes are lighter than air and spreads quickly. It is usually sold industrially as a fluid setting containing 2 to 10% hydrogen cyanide. Cyanide hydrogen arrangements are gradually damaged to form an ammonium format. It is a very toxic gas with a bitter almond odour. It is a malicious transparent liquid; Storage and transportation are not allowed.

It is also known as – Prussic acid, acetonitrile, formonitrile.

Properties of Hydrocyanic Acid

HCN

Hydrocyanic acid

Density

687 kg/m³

Molecular Weight/ Molar Mass

27.0253 g/mol

Boiling Point

25.6 °C

Melting Point

-13.4 °C

Chemical Formula

HCN

Structure of Hydrocyanic Acid

Physical Properties of HCN

  • Have a bitter almond smell in it
  • Having a pale blue appearance 
  • Have a covalently bond unit as 2
  • Having heat capacity of 35.9 J K−1 mol−1
  • Hydrogen bond donor as 1
  • Miscible in water and ethanol

Chemical Properties of HCN

  • Hydrocyanic corrosive responds with a base like sodium hydroxide structures sodium cyanide and water. The synthetic condition is given underneath. 

                                                            HCN + NaOH → NaCN + H2O 

  • Hydrocyanic corrosive responds with potassium hydroxide structure, potassium cyanide, and water. The synthetic condition is given underneath. 

                                                             HCN + KOH → H2O + KCN

Uses of Hydrocyanic Acid

  • Utilized as a fragment to execute nuisances, for example, rodents in stockrooms, grain stockpiling containers, nurseries, and holds of boats where its high harmfulness and capacity to enter dark spaces are invaluable. 
  • Utilized in the production of cyanide salts, acrylonitrile, and colors. It is likewise utilized as a plant fumigant. 
  • Utilized as a profoundly important forerunner in the creation of a few synthetic substances.

Occurrence: HCN can be obtained from fruits with holes, such as cherries, apricots, apples, and bitter almonds, from which almond oil and seasoning are made. Many of these holes contain small amounts of cyanohydrin such as mandelonitrile and amygdalin, which slowly releases hydrogen cyanide. One hundred grams of crushed apple seeds can produce around 70 mg of HCN. Some milpedia releases hydrogen cyanide as a defense mechanism, like certain insects, like some burnet moths.

Hydrocyanic Acid in class 11

In this class 11, the hydrocyanic acid has been discussed in the chapter on equilibrium, with its formula, reactions with other multiple compounds, and its properties.

The chapter has a weightage of 20 Marks.

Illustrated Examples

1. Give the reaction between aqueous hydrocyanic acid and aqueous sodium hydroxide

Answer: HCN(aq) + OH^-(aq) ---> H2O(l) + CN^-(aq)

HCN is written in a sub-atomic manner since it is a feeble corrosive and ionizes just a limited quantity. NaOH, then again, is a solid electrolyte, ionizing 100% in the arrangement. The Na^+ is an observer particle, so it is not written in the net ionic condition.

2. Give the reaction between hydrocyanic acid and ammonia.

Answer: HCN(aq) + NH3(aq) → ← NH4+(aq) + CN–(aq)

3. Give the reaction between hydrocyanic acid and hydrogen

Answer: H+ + NaCN → HCN + Na+

FAQs on Hydrocyanic Acid

Q: How can we say that hydrocyanic acid is very poisonous in nature?

A:  Hydrocyanic corrosive is the arrangement of hydrogen cyanide in water. It is a profoundly noxious synthetic, additionally called prussic corrosive. The substance equation of hydrocyanic corrosive is HCN.

Q: For what reason do we use hydrocyanic acid?

A:  Regardless of its poisonousness, HCN is a significant reagent utilized to create an assortment of helpful modern synthetics.

Q: How strong is hydrocyanic acid?

A:  HCN (hydrocyanic acid) is the weakest base, but its conjugate base CN- (cyanide ion) is the strongest.

Q: Can we say that HCN is better than water in acidity?

A:  Of these acids, the most grounded is HF, as it has the biggest Ka. Hydrocyanic is the most fragile of the gathering as it has the littlest Ka. This implies that HF will separate undeniably when set in water than different acids. HCN will separate the least.

Q: What acid is stronger HF or HCN?

A:  HF is a stronger acid than HCN. The conjugate base of HF is fluoride ion. HF has a higher tendency to donate a proton to water than does HCN.

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