Barium Hydroxide: Overview, Questions, Preparation

The p-Block Elements

Updated on Apr 27, 2021 01:34 IST

Introduction

Barium Hydroxide is a white granular compound. It consists of water and barium oxide. It is predominantly used for the production of other things from Barium. One of the major derivatives of the element barium is the monohydrate known as baryta or baryta-water.

Barium Hydroxide's Chemical Composition

Barium Oxide's chemical formula is interesting because of the chemical formula of Barium Hydroxide. Barium Hydroxide is made up of barium and hydroxide. So, technically speaking, Ba should be the formula (OH). Then, why do we write the formula of Barium Hydroxide as  Ba(OH)2? This is because there are two positive ions of Barium and a negative one in hydroxide. So, we add another hydroxide to Barium Hydroxide and render it neutral to demonstrate Barium as a neutral compound.

Barium Hydroxide Properties

The properties of Barium Hydroxide are as follows: 

  • Molar Mass

The molar mass of Barium Hydroxide is 171.344g/mol

  • Melting Point

The melting point of Barium Hydroxide varies according to the amount of water it contains. Barium oxide's octahydrate phase melts at 78 degrees Celsius. At 300 degrees Celsius, the monohydrate phase melts, and the anhydrous form melts at 407 degrees Celsius

  • Solubility

Barium Hydroxide is only partially soluble in water

  • Boiling Point

Barium Hydroxide boils at 780 degrees Celsius. It would decompose and give out barium oxide if you manage to boil it. For this, the temperature should exceed 800 degrees Celsius.

Uses of Barium Hydroxide

  • Barium Hydroxide lime is popularly used as an alternative to soda lime. The compound is present in high concentration in sevoflurane
  • It is used to produce alkalis, glass, oil and grease additives, barium soaps, and other barium compounds

Physical Properties of Barium Hydroxide

Odour

No odour

Appearance

White solid

Covalently-Bonded Units

Three

Vapour Pressure

0.48 kPa at 17.6 C

pH

11.27

Solubility

Partially soluble in water

Barium Hydroxide in Class 11:

In the p-block elements chapter, you will learn about barium and its compounds. The weightage of this chapter is 5-6 marks in class 11.

Illustrated Examples:

  • What is the molecular mass of Barium Hydroxide?

Mass of Barium = 137.33 gm/mol

Mass of Oxygen = 16g/mol  = 32gm because of 2 moles

Mass of Hydrogen = 1g/mol = 2gm because of 2 moles

Adding all of these = 171.33 gm/mol

  • How is the preparation of barium hydroxide done?

Usually, barium hydroxide is made in water by dissolving barium oxide (chemical formula: BaO). The chemical equation is given below for this reaction:

BaO + 9 H2O → Ba(OH)2·8H2O

  • Find the pH level of a 0.10 M solution of Barium Hydroxide.

Solution: 

Ba(OH)2 (s) →Ba2++ 2OH

The solution will have 0.20 M of hydroxide ions

[H+][OH]=1.0×10−14M

[OH]=2.0×10−1M

[H+]=5.0×10−14M

pH = −log10([H+]=5.0×10−14) = 13.30

FAQs on Barium Hydroxide

Q. Is Barium Hydroxide a base or an acid?

A.  Barium Hydroxide is a stable base, like NaOH and KOH. Barium Hydroxide is a group IIA metal hydroxide that is water-soluble to give a good base solution such as group IA metal hydroxides. Barium Hydroxide is fully dissolved in water and comprises barium ions and hydroxyl ions.  

Q. Is Barium Hydroxide aqueous?

A.  Barium Hydroxide is used in analytical chemistry to titrate weak acids, especially organic acids. Unlike alkali hydroxides, it forms clear, aqueous solutions that are carbonate-free since Barium Carbonate is insoluble in water.  

Q. What's the charge on Ba(OH)2?

A.  In Group 2, Barium is an atom, so it has two valence electrons, and its charge is 2+. Hydroxide is a negative polyatomic ion with a value of 1, and 1- is the charge. They mix to form an ionic compound as Barium is metal and Hydroxide is a non-metal.  

Q. Which base is the strongest?

A.  The strongest base is Sodium Hydroxide since it dissociates entirely to supply sodium ions and hydroxide ions. These hydroxide ions react with the acid's hydrogen ions and ionise the hydrogen ions completely.  

Q. What is the chemical name of Barium Hydroxide?

A.  It is Ba(OH)₂ₓ  

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