Difference between Alcohol and Phenol: Overview, Questions, Preparation

Alcohols, Phenols and Ethers

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Updated on Apr 17, 2021 02:21 IST

What is alcohol?

Alcohol is one of the most commonly found compounds in nature. They contain at least one hydroxyl functional group (-OH) attached to a carbon atom of a hydrocarbon or an alkyl group. Further, the type of carbon attached to the hydroxyl group determines whether the alcohol is a primary, secondary, or tertiary compound. 

Structure of alcohol:

Structure of Alcohol

Properties of Alcohol

Some of the physical properties of alcohol are as follows:

  • Boiling point: Alcohols have slightly higher boiling points due to the presence of hydrogen bonds between the hydroxyl groups
  • Solubility: Alcohols are soluble in water if the hydrogen bonds are hydrophilic and form hydrogen bonds with water
  • Acidity: Alcohol reacts with sodium, potassium, and other active metals to form alkoxides. These reactions indicate its acidic nature

What is a phenol?

Phenols or phenolics are chemical compounds that consist of a hydroxyl group attached to an aromatic hydrocarbon. They are known as a subset of alcohol but exhibit different physical and chemical properties in comparison. They are also called carbolic acids and are used to prepare nylons, herbs, detergents, and other pharmaceutical products.

Structure of Phenol

Phenol Structure

Properties of Phenol

Some of the physical properties of phenol are as follows:

  • Boiling point: Phenols exhibit a higher boiling point than most other hydrocarbons
  • Solubility: Phenols are soluble in water
  • Acidity: Phenols also react with sodium, potassium, and other active metals to form phenoxides. These reactions indicate its acidic nature

Difference between alcohol and phenol

We know that phenol is sometimes considered a type of alcohol. However, various factors can help us differentiate between the two compounds. Some of the differentiating factors between alcohols and phenols are as follows:

ALCOHOL

PHENOL

Alcohol is an organic compound that contains one or more hydroxyl functional groups attached to a saturated carbon atom

Phenols are organic compounds that consist of a hydroxyl group attached to a group of hydrocarbons or arene

Alcohol consists of aliphatic hydrocarbons

Phenol consists of aromatic hydrocarbons

Alcohols are less acidic

Phenols are more acidic in comparison with alcohol and need to be diluted before use

Alcohol is used as an ingredient in alcoholic beverages, ink, pharmaceuticals, and various other chemical products

Phenols are commonly used as antiseptic agents

Alcohols are colourless and are found in the liquid state

Phenols are also colourless but are crystalline at standard temperature and pressure

Alcohols are neutral and hence, show no reaction on litmus paper or other tests

Phenols are acidic and change the colour of litmus paper to red

Alcohols do not react with sodium hydroxide (NaOH)

Phenols react with sodium hydroxide (NaOH) to form phenoxides

Alcohols and Phenols in class 11: In class 11, the basic structure and reaction of different compounds with alcohols and phenols are mentioned in various chapters.

Alcohols and phenols in class 12: The chapter on Alcohols, Phenols, and Ether in class 12 includes a complete and detailed explanation of alcohols and phenols. It consists of a thorough explanation of the physical and chemical properties of alcohols and phenols. 

The chapter also discusses the reactions involved in the preparation of these compounds and correlates the physical properties with their structure.

FAQs regarding Alcohols and Phenols

Q. What are the different methods for the preparation of alcohol?

A. Alcohols are prepared through the hydrolysis of halides, hydration of alkanes, and hydroboration of alkenes.

Q. What are the different compounds used for the preparation of phenol?

A. Phenols are prepared using haloarenes, benzene sulphonic acids, cumene, and diazonium salts.

Q. Are alcohols and phenols polar?

A. Yes, both alcohols and phenols are polar.

Q. Can alcohols and phenols be oxidized?

A. Yes, both phenols and alcohols can undergo oxidization.

Q. Who discovered phenol?

A. Phenol was discovered in 1834 by a German chemist Dr. Friedlieb Ferdinand Runge.  

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