Hydroiodic Acid: Overview, Questions, Preparation

Redox Reactions

Updated on May 11, 2021 02:05 IST

The hydroiodic corrosive also called the hydronic corrosive is tasteless gas, which changes the Lakmus into a reddish colour, and produces thick white exhaust in the wet air. The compound equation for hydroiodic corrosive is Hi. Hydroiodic acid is solid acid made by dissolving iodide hydrogen in water. However, the difference is one gas, and the other is water. 

It is one of the strongest of all ordinary halide acids because of the conjugate base's high stability. It is also called hydrogen iodide and iodane.

Properties of Hydroiodic Acid

Particulars

Values

HI

Hydroiodic acid

Density

1,700 g/cm³

Molecular Weight/ Molar Mass

127.911 g/mol

Boiling Point

-35.36 °C

Melting Point

-51 °C

Chemical Formula

HI

Structure of Hydroiodic Acid

Hydroiodic acid structure

Hydroiodic Acid Physical Properties

  • Have a pungent odour
  • Colourless liquid appearance
  • Having covalent bond=1
  • The heat of evaporation is 17.36 kJ/mol @ 25 deg C
  • Have a hydrogen bond donor as 1
  • Soluble in water

Hydroiodic Acid Chemical Properties

  • Hydroiodic corrosive responds with seething nitric corrosive structures iodine, nitrogen oxide, and water. The compound condition is given below. 

                                            2HNO3 + 6HI → 2NO + 3I2 + 4H2O 

  • Hydroiodic corrosive responds with a base say sodium hydroxide structures sodium iodide and water. The substance condition is given below. 

                                  HI + NaOH → NaI + H2O

  •  Hydroiodic acid reacts with oxygen in the air to give iodine:

4 HI + O2 → 2 H2O + 2 I2

Like other hydrogen halides, hydroiodic acid adds to the alkene to give alkyl iodide. It can also be used as reducing agents, for example in reducing aromatic nitro compounds to Aniline

Hydroiodic Acid Uses

  • Used in the assembling of iodides and as a diminishing specialist and in disinfectants and drugs. 
  • Used as one of the essential wellsprings of iodine in natural and inorganic blends. 
  • Hydroiodic corrosive furthermore of potassium iodide, a consistent decision as a wellspring of a nucleophile in ketal deprotection.

In Class 11: In the chapter Redox Reaction, the acid has been discussed in depth with its reactions, usage, and properties in everyday chemistry. It has a weightage of 20 Marks.

Illustrated Examples

  • The propionic corrosive is exposed to decrease with hydroiodic corrosive within the sight of a little P. The item that we will get accordingly may be:

Propane

[H+] = 10-2.08 = 0.00832 mole/L

0.00832 mole/L X 0.775 L = 0.00645 mole HI

0.00645 mole HI X 127.9 g/mole = 0.824 g

  • CH3)3COCH3 and CH3OC2H5 are treated with hydroiodic acid. What will be the result?

(CH3)3CI + CH3OH; CH3I + C2H5OH

  • What will form when HI and HNO3 react?
Reaction of HI and HNO3

FAQs on Hydroiodic Acid

Q. What are the health hazards of Hydroiodic acid?

A.  Hydroiodic corrosive is a destructive fluid that in contact with the skin can create cons. Corrosive contact with the eyes may cause serious bothering. A solid aggravation to the eyes, skin, and mucous films is the gas hydrogen iodide.

Q. What about its electron affinity while creating the buffer?

A.  The electron partiality of the iodine particle isn't very different from those of the other halogen iotas. Iodine is a more vulnerable oxidizing specialist than bromine, chlorine, or fluorine. The accompanying response—oxidation of arsenite, (AsO 3 ) 3− in fluid arrangement continues just within the sight of sodium hydrogen carbonate, which goes as: 


In the acidic arrangement, arsenate, (AsO4)3−, is decreased to arsenite, though, in the emphatically soluble arrangement, iodine is unsteady, and the opposite response happens.

Q. What is the pH of the hydroiodic acid?

A.  The pH of the hydroiodic corrosive 1.85. Hydroiodic corrosive is a solid corrosive with equation HI.  

Q. What is the preparation of the acid?

A.  Hydroiodic corrosive is arranged financially by the response of iodine (I2) with hydrazine, giving hydrogen iodide and nitrogen gas. 

                                              2 I2 + NH2NH2 → 4 HI + N2 

Hydroiodic corrosive is additionally set up by gurgling hydrogen sulfide gas through a watery arrangement of iodine.

                                               H2S + I2 → 2 HI + S 

Toward the finish of the response, HI is refined to give hydroiodic corrosive in the ideal fixations.  

Q. Is Hydoiodic acid strong?

A. Hydroiodic acid is a strong acid , one that is ionized completely in an aqueous solution. It is colorless. Concentrated solutions are usually 48 - 57% HI .

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