Eugenol: Overview, Questions, Preparation

Alcohols, Phenols and Ethers

Updated on Apr 17, 2021 06:20 IST

What is Eugenol?

Eugenol is a weak acid having the chemical formula C10H12O2. It is a yellow pale-coloured allyl chain substituted with guaiacol. It is an aromatic oil extracted from essential oils like clove oil, cinnamon, basil, bay leaf, and nutmeg. The concentration of clove oil is between 82-88 %.

 Eugenol's name is derived from the former nomenclature of clove which is 'eugenia caryophyllata’.

 One of the major components of clove oil is phenylpropanoids, and eugenol is the reduced version of it. It has multiple uses and can be used for skin purposes, if added indirectly. However, if taken indirectly, it could be harmful to the skin and backfire, as essential oils should not be applied to the skin directly. The exposure of eugenol to direct air makes the consistency of it thicker and darker, which is relative to the time it is exposed to air.

Eugenol

Properties of Eugenol

Chemical formula

C10H12O2

Molar mass

164.2 g/mol

Density

1.06 g/cm³

Boiling point

254 °C

Melting point

-7.5 °C

Acidity

10.19 at 25 °C

 Physical Properties of Eugenol

Complexity

145

Hydrogen bond donor

1

Solubility level

High with oils, alcohol

Appearance

Pale yellow colour

Odour

Similar to clove leaves

 Uses of Eugenol

  1. Eugenol is used in perfumes because of its aromatic smell.
  2. It is also used in the manufacturing of local antiseptics and healers.
  3. It is used as a bait to attract and study bees.
  4. Food industries often use eugenol for food additives and food colourings.
  5. One of the oldest used cement is zinc oxide eugenol; it produces a marginal seal than others and has been used for many years.
  6. Essential oils being one of the main markets for the abundant use of eugenols, there are certain modifications of eugenol at a chemical level that are being done by experts to make it more suitable for patients and their needs.

Chemical Properties of Eugenol

With iron and chloride, eugenol undergoes a double displacement reaction as follows:

C10H12O2 + FeCl3 → C10H9O2Fe + 3HCl

After reacting with bromine, eugenol forms oxygen and 1,3 – dibromo butyl benzene. The chemical reaction of this is as follows:

C10H12O2 + Br2 → C10H12Br2 + O2

Eugenol in Class 11

For the year 2021, the chapter on alcohol, phenol, and ethers holds a weightage of 6 marks, including one very short question (2 marks), one short question (3 marks), and one objective type question (1 mark).

FAQs regarding Eugenol

Q. What is the molar mass or molarity of eugenol?

A.  The molar mass or molarity of eugenol is 164.2 g/mol.

Q. Is eugenol toxic to use?

A.  Eugenol can be toxic, unlike other essential oils. If it is taken or applied directly onto the skin, then it is considered a toxic solution. However, if applied indirectly or in a small ratio, it would not harm the skin, but it is advised to contact the doctor.

Q. Is eugenol soluble in water?

A.  No, eugenol is not soluble in water. However, it is miscible in alcohol and oil.

Q. Which essential oils are present in eugenol?

A.  Clove oil, nutmeg, bay leaf, basil leaf, and cinnamon are all present in eugenol.

Q. What is the chemical formula of eugenol?

A.  The chemical formula of eugenol is C 10 H 12 O 2.  

Q. What is the IUPAC name for the weakly acid compound eugenol?

A.  The IUPAC name for eugenol is 2-methoxy-4-prop-2-enylphenol.

Q. What is the vapour density of eugenol?

A.  The vapour density of ethanol is relative to air but can be determined as (greater than) >1.0 .

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