Ideal Solution: Overview, Questions, Preparation

Atoms and Molecules 2023 ( Atoms and Molecules )

Salviya Antony

Salviya AntonySenior Executive - Content

Updated on Oct 19, 2023 13:50 IST

Ideal Solution: We can define an ideal solution as a solution where the interaction of component molecules does not vary from the interactions of each component’s molecules. At all concentrations and temperatures, ideal solutions obey Raoult’s law. Chlorobenzene and bromobenzene, methanol and ethanol, benzene and toluene, n-butyl chloride and n-butyl bromide, etc are examples of ideal solutions. 

Class 12 students will learn ideal solution in the chapter Solutions in NCERT Class 12 Chemistry. Ideal solution refers to a mixture or solution in which the components mix perfectly and exhibit ideal behaviour. In an ideal solution, the interactions between the molecules of the components are very similar, and there are no deviations from Raoult's Law. An ideal solution is a mixture in which the molecules of different species are distinguishable, however, unlike the ideal gas, the molecules in ideal solution exert forces on one another. When those forces are the same for all molecules independent of species then a solution is said to be ideal. 

Raoult's Law states that the partial vapour pressure of each component in an ideal solution is directly proportional to its mole fraction in the solution. In other words, the behaviour of the components in an ideal solution is predictable and follows simple mathematical relationships. Ideal solutions are often used as a theoretical benchmark in the study of real solutions to understand deviations from ideal behaviour.

 

Ideal Solution: Properties

  • There is no energy change (neither absorption nor release) when the components mix.
  • The volume of the mixing is zero. Δmix V = 0
  • The enthalpy of mixing is zero, meaning there is no heat involved in the mixing process. Δmix H = 0

It's important to note that ideal solutions are an idealization and do not typically exist in the real world. Real solutions often deviate from the behaviour described by Raoult's Law due to variations in molecular interactions, non-ideal mixing, and other factors. These deviations can be particularly significant when dealing with mixtures of polar and nonpolar substances or when there are strong intermolecular forces between the components.

Ideal and Non-Ideal Solution: Difference

Students can check the difference between ideal and non ideal solution below.

Ideal Solution Non ideal Solution
Ideal solution obeys Raoult’s law Non Ideal solution does not obeys Raoult’s law
Ideal solution components can be separated by fraction distillation Cannot separate Non-ideal solution components using fraction distillation
Change in enthalpy is zero when an ideal solution is formed Change in enthalpy may be positive or negative in case of non-ideal solution. It is not zero.
Interactions between the components in an ideal solution are similar to those in the pure components. Interactions between the components in non-ideal solutions are different from those of the pure components.
Chlorobenzene and bromobenzene, n-butyl chloride and n-butyl bromide, methanol and ethanol, benzene and toluene, etc are examples of Ideal solution. Sugar solution, kerosene, ethanol and acetone, chloroform and acetone etc are examples of non Ideal solution.

FAQs on Ideal Solution

Q: Vapour pressures of pure acetone and chloroform at 328 K are 741.8 mm Hg and 632.8 mm Hg respectively. Assuming that they form ideal solution over the entire range of composition, plot ptotal, pchloroform, and pacetone as a function of xacetone. The experimental data observed for different compositions of mixture is: Plot this data also on the same graph paper. Indicate whether it has positive deviation or negative deviation from the ideal solution.

A:

100 xacetone

0

3.4.8

23.4

36.0

50.8

58.2

64.5

72.1

pacetone /mm Hg

0

54.9

110.1

202.4

322.7

405.9

 454.1

521.1

pchloroform /mm Hg

632.8

548.1

469.4

359.7

257.7

193.6

161.2

120.7

A 2.37 The Ptotal for the values given in the graph is found out and plotted in the graph.

ptotal(mm Hg)

632.8

603.0

579.5

562.1

580.4

599.5

615.3

641.8

It can be observed from the graph that the plot for the total of the solution curves downwards. Therefore, the solution shows negative deviation from the ideal behaviour.

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